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Radical stabilization energies in esters. .beta.-Carbomethoxy group from kinetics of the thermal isomerization of 1-chloro-4-carbomethoxybicyclo[2.2.0]hexane in the liquid phase

โœ Scribed by Cain, Edward N.; Solly, Richard K.


Book ID
127059971
Publisher
American Chemical Society
Year
1973
Tongue
English
Weight
769 KB
Volume
95
Category
Article
ISSN
0002-7863

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Gas and liquid phase kinetics of the uni
โœ Edward N. Cain; Richard K. Solly ๐Ÿ“‚ Article ๐Ÿ“… 1972 ๐Ÿ› John Wiley and Sons ๐ŸŒ English โš– 530 KB

The kinetics of the gas phase isomerization of l-chloro-4-bromobicyclo[2.2.O]hexane to 2-chloro-5-bromohexa-1,5diene have been measured in a static system over the temperature range of 135-215"C, with a variation in the total pressure from 0.6 to 400 torr. For these conditions, the rate constants ar