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Radical reactivity of 2,2,6,6,-tetramethylpiperidine derivatives: A kinetic ESR study

โœ Scribed by A. Faucitano; A. Buttafava; F. Martinotti; F. Gratani; P. Bortolus


Book ID
116092594
Publisher
Elsevier Science
Year
1985
Weight
379 KB
Volume
6
Category
Article
ISSN
0144-2880

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The irradiation of 4-hydroxy-2,2,6,6-tetramethylpiperidine (I) by x-rays produces radicals at both the nitrogen and oxygen atoms in the molecule. With short irradiation times the nitrogen radical is produced but with longer exposures the oxygen radical is predominant. This occurs in the powder sampl