𝔖 Bobbio Scriptorium
✦   LIBER   ✦

Radical reactions of highly polar molecules. Chlorination of halopropanes

✍ Scribed by Leonard O. Moore; Charles E. Rectenwald; Jared W. Clark

Publisher
John Wiley and Sons
Year
1972
Tongue
English
Weight
317 KB
Volume
4
Category
Article
ISSN
0538-8066

No coin nor oath required. For personal study only.

✦ Synopsis

In polychloro-2,2-difluoropropanes, where a large inductive effect results in relatively low reactivity to chlorination, the presence of additional chlorine causes an increased reactivity of the hydrogens geminal to the chlorine and a reduced reactivity of the remote (third carbon) hydrogens. The ways in which resonance, inductive effect, and steric crowding interact in the rates of chlorination of polar molecules are discussed.

πŸ“œ SIMILAR VOLUMES

Reactions of strongly polar ions with mo
Reactions of strongly polar ions with molecules
✍ David C. Clary πŸ“‚ Article πŸ“… 1995 πŸ› Elsevier Science 🌐 English βš– 366 KB

A theoretical study is reported on the effect of various long-range terms in the potential energy surface on the rate constants for the reactions of strongly polar ArH~-with H20 and NH3. A rotationally adiabatic capture theory is used. It is found that dipole-dipole, dipole-induced dipole and disper

Correlation of activation energies of ra
Correlation of activation energies of radical–molecule metathesis reactions with enthalpic, polar, and steric parameters
✍ M. G. Katz; L. A. Rajbenbach πŸ“‚ Article πŸ“… 1978 πŸ› John Wiley and Sons 🌐 English βš– 881 KB

## Abstract It is shown that the activation energies __E__ oF chlorine atom abstraction by cyclohexyl radicals and hydrogen atom abstraction by Cl atoms from polychloroalkanes can be correlated with the bond dissociation energies __D__ and the Taft polar and steric substituent constants Οƒ\* and __E