✦ LIBER ✦
Radical reactions of (2-trimethylsilylallyl)triphenylstannane with alkyl halides: A neutral acetone enolate equivalent
✍ Scribed by Eun Lee; Sang-Gu Yu; Chang-Uk Hur; Seung-Min Yang
- Book ID
- 104221807
- Publisher
- Elsevier Science
- Year
- 1988
- Tongue
- French
- Weight
- 117 KB
- Volume
- 29
- Category
- Article
- ISSN
- 0040-4039
No coin nor oath required. For personal study only.
✦ Synopsis
Facile transfer of 2-trimethylsilylallyl group is achieved when (2-trimethylsilylallyl)triphenylstannane is reacted with some halides under radical reaction conditions.
Recently, allylstannanes were developed into useful synthetic reagent; in particular, they were used in free radical reactions with alkyl halides, which provided a method for replacing the halogen atom by an ally1 group.