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Radical reactions in pyrolysis of triethylarsine and diethylarsine

โœ Scribed by S.H. Li; C.A. Larsen; G.B. Stringfellow

Book ID
103166833
Publisher
Elsevier Science
Year
1991
Tongue
English
Weight
875 KB
Volume
112
Category
Article
ISSN
0022-0248

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Reactions of the iso-butyl radical durin
Reactions of the iso-butyl radical during 1,1โ€ฒ-azoisobutane pyrolysis
โœ G. McKay; J. M. C. Turner ๐Ÿ“‚ Article ๐Ÿ“… 1978 ๐Ÿ› John Wiley and Sons ๐ŸŒ English โš– 559 KB

Quantitative analysis of the products formed in 1,l'-azoisobutane pyrolyses in the temperature range of 553"-602"K has shown that the major reactions of the iso-butyl radical are kc 2iC4H9 -2,5 dimethyl hexane and k4 (4) iC4H9 -CH3 + C3H6 Analysis of initial rate data gave loglo k~/(kc)1~2(~m-3~2~m~