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Radical polymerizations involving esters of vinyl alcohol—I Reactivities of monomers towards the benzoyloxy radical

✍ Scribed by J.C. Bevington; M. Johnson

Publisher
Elsevier Science
Year
1968
Tongue
English
Weight
142 KB
Volume
4
Category
Article
ISSN
0014-3057

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✦ Synopsis

l*C-benzoyl peroxide has been used at 60 ° to initiate polymerizations of vinyl formate, propionate, butyrate, benzoate and phenyl acetate at various concentrations in benzene. The relative numbers of benzoyloxy and phenyl end-groups in the various polymers have been determined; these numbers have been used to deduce the relative reactivities of the monomers towards the benzoyloxy radical.

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