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Radical polymerization of diethylaminoethyl methacrylate and its salts in various solvents

✍ Scribed by Ye.V. Bune; A.P. Sheinker; Yu.S. Bogachev; I.L. Zhuravleva; E.N. Teleshov

Publisher
Elsevier Science
Year
1991
Tongue
English
Weight
389 KB
Volume
27
Category
Article
ISSN
0014-3057

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✦ Synopsis

NMR-spectral data for diethylaminoethyl methacrylate and its salts in various solvents have been considered with the kinetics of polymerization of these monomers. The data on the interaction of a monomer with a solvent obtained using NMR-spectroscopy lead to ideas about the effect of the formation of hydrogen bond between solvent and monomer molecules, protonization and ionization of the monomer on its reactivity in the polymerization. The effect of various conformations of growing polymer chains upon the rate of polymerization is also very important.

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