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Radical polymerization activity and mechanistic approach in a new three-component photoinitiating system

โœ Scribed by J. P. Fouassier; X. Allonas; J. Lalevee; M. Visconti


Publisher
John Wiley and Sons
Year
2000
Tongue
English
Weight
248 KB
Volume
38
Category
Article
ISSN
0887-624X

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Three-component systems, which contain a light-absorbing species (typically a dye), an electron donor (typically an amine), and a third component (usually an iodonium salt), have emerged as efficient, visible-light-sensitive photoinitiators. Although three-component systems have been consistently fo

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Photo-DSC and in situ, time-resolved, laser-induced, steady-state fluorescence spectroscopy were used to study the initiation mechanism of the three-component system: Eosin Y spirit soluble (EYss), N-methyldiethanolamine, and diphenyliodonium chloride. Kinetic studies based on photo-DSC revealed tha