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Radical-mediated hydroxytrifluoromethylation of α,β-unsaturated esters

✍ Scribed by Tomoko Yajima; Hajime Nagano; Chiaki Saito

Publisher: Elsevier Science
Year: 2003
Tongue: French
Weight: 119 KB
Volume: 44
Category: Article
ISSN: 0040-4039
DOI: 10.1016/s0040-4039(03)01783-0

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✦ Synopsis

Treatment of a,b-unsaturated esters with trifluoromethyl iodide and triethylborane in the presence of KF and H 2 O gave the corresponding hydroxytrifluoromethylated esters.

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