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Radical Mechanisms of the Decomposition of Peroxynitrite and the Peroxynitrite–CO2 Adduct and of Reactions with l-Tyrosine and Related Compounds as Studied by 15N Chemically Induced Dynamic Nuclear Polarization

✍ Scribed by Manfred Lehnig

Book ID
115567683
Publisher
Elsevier Science
Year
1999
Tongue
English
Weight
152 KB
Volume
368
Category
Article
ISSN
0003-9861

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15N Chemically Induced Dynamic Nuclear P
15N Chemically Induced Dynamic Nuclear Polarization (15N-CIDNP) Investigations of the Peroxynitrite Decay and Nitration of N-Acetyl-L-tyrosine
✍ Manfred Lehnig; Michael Kirsch 📂 Article 📅 2006 🏛 John Wiley and Sons 🌐 German ⚖ 270 KB 👁 1 views

## Abstract During the decay of (^15^N)peroxynitrite (O^15^NOO^−^) in the presence of __N__‐acetyl‐L‐tyrosine (Tyrac) in neutral solution and at 268 K, the ^15^N‐NMR signals of ^15^NO$\rm{\_2^ - }$ and ^15^NO$\rm{\_3^ - }$ show emission (__E__) and enhanced absorption (__A__) as it has already bee