Radical mechanism of aromatic ‘nucleophilic’ substitution

✍ Scribed by Ramesh Kumar; P.R. Singh

• Publisher: Elsevier Science
• Year: 1972
• Tongue: French
• Weight: 239 KB
• Volume: 13
• Category: Article
• ISSN: 0040-4039
• DOI: 10.1016/s0040-4039(01)84391-4

✦ Synopsis

Recently, Kim and Bunnett' and we3 simultaneously proposed a new radical some reactions which formally appear to be aromatic nucleophilic substitutions.

further support from the results of our studies on the uncatalysed reactions of benzenediazonium cations with the iodide ion as reported in this communication.

mechanism for

These views find

E-substituted

Our observations on the reaction of p-nitrobensenediasonium fluoborate with potassium iodide under different conditions are susmuzrized in Table I.