Radical Ion Probes. 9. The Chemistry of Radical Cations Derived from 9-Cyclopropylanthracene and 9-Bromo-10-cyclopropylanthracene
โ Scribed by Wang, Yonghui; McLean, Karen H.; Tanko, J. M.
- Book ID
- 121397063
- Publisher
- American Chemical Society
- Year
- 1998
- Tongue
- English
- Weight
- 212 KB
- Volume
- 63
- Category
- Article
- ISSN
- 0022-3263
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๐ SIMILAR VOLUMES
Flash photolysis of bis [4,5di(methylsulfanyl)1,3-dithiol-2-ylidene]-9,10-dihydroanthracene (1) in chloroform leads to formation of the transient radical cation species 1 . which has a diagnostic broad absorption band at l max % 650 nm. This band decays to half its original intensity over a period o
The optical detection (OD) ESR and Freon matrix ESR spectra were observed for the radical cations of 9,lO-octalin and cyclohexene from 77 to 300 K. The observed spectral change was attributed to ring inversion in both radical cations based on MO calculations and an analysis by the modified Bloch equ