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Radical-initiated homopolymerization and copolymerization of ethyl α-hydroxymethylacrylate

✍ Scribed by Mitsuru Ueda; Toshitaka Koyama; Motokazu Mano; Masahiko Yazawa


Book ID
105337149
Publisher
John Wiley and Sons
Year
1989
Tongue
English
Weight
491 KB
Volume
27
Category
Article
ISSN
0887-624X

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✍ Duygu Avci; Lon J. Mathias; Kevin Thigpen 📂 Article 📅 1996 🏛 John Wiley and Sons 🌐 English ⚖ 768 KB

Several new benzoate ester derivatives of ethyl a-hydroxymethylacrylate were synthesized using phase transfer catalysis and found to display unexpectedly rapid photopolymerization; i.e., from 2 to 8 times faster than MMA. New derivatives described here include the 4fluoro-, 4-trifluoromethyl-, 4-met