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Radical Desorption Kinetics in Emulsion Polymerization. 1. Theory and Simulation

✍ Scribed by Hernandez, Hugo F.; Tauer, Klaus

Book ID
127219732
Publisher
American Chemical Society
Year
2008
Tongue
English
Weight
274 KB
Volume
47
Category
Article
ISSN
0888-5885

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πŸ“œ SIMILAR VOLUMES

Radical Desorption Kinetics in Emulsion
Radical Desorption Kinetics in Emulsion Polymerization, 2 – Brownian Dynamics Simulation of Radical Desorption in Non-Homogeneous Particles
✍ Hugo F. Hernandez; Klaus Tauer πŸ“‚ Article πŸ“… 2010 πŸ› John Wiley and Sons 🌐 English βš– 444 KB

## Abstract One of the most important events in free‐radical emulsion polymerization is desorption of radicals from the polymer particles to the aqueous phase. Desorption takes place by diffusion of radicals inside the particle toward the surface and transfer to the aqueous phase. The rate of desor

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## Abstract Analysis of published experimental data on monomeric radical diffusion in the emulsion polymerisation of styrene shows that it can be quantitatively described equally well by non‐equilibrium diffusion from particles, where all parameters are derived from properties of the discrete phase