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Radical cyclizations of bromo ketals from decalin homoallylic and bis-homoallylic alcohols

✍ Scribed by Guillermo R Labadie; Raquel M Cravero; Manuel González-Sierra

Book ID: 104230133
Publisher: Elsevier Science
Year: 2001
Tongue: French
Weight: 100 KB
Volume: 42
Category: Article
ISSN: 0040-4039
DOI: 10.1016/s0040-4039(01)00048-x

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✦ Synopsis

The radical cyclizations of bromo ketals derived from the Birch-alkylation products of a-tetralones are described. The carbon carbon bond formation proceeds in a regio-and stereoselective way. The intra-and intermolecular trapping behavior was also explored.

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