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Radical cyclization of β-alkoxyacrylates: Synthesis of a C2-symmetric, L-shaped molecule with four fused tetrahydropyran rings

✍ Scribed by Eun Lee; Hee Jo Kim; Eun Joo Kang; In Su Lee; Young Keun Chung

Book ID: 101297495
Publisher: John Wiley and Sons
Year: 2000
Tongue: English
Weight: 101 KB
Volume: 12
Category: Article
ISSN: 0899-0042
DOI: 10.1002/(sici)1520-636x(2000)12:5/6<360::aid-chir10>3.0.co;2-1

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✦ Synopsis

A C2-symmetric, L-shaped tetracycle with four fused tetrahydropyran rings was synthesized from (3R, 4R)-1, 6-dibenzoyloxy-hexane-3, 4-diol employing radical cyclization reactions of beta-alkoxyacrylates.