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Radical cyclisation approach for the synthesis of (+)dihydrocanadensolide, (+)dihydrosporothriolide and their C-3 epimers from d-xylose

✍ Scribed by G.V.M Sharma; T Gopinath

Publisher: Elsevier Science
Year: 2003
Tongue: French
Weight: 295 KB
Volume: 59
Category: Article
ISSN: 0040-4020
DOI: 10.1016/s0040-4020(03)01068-8

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✦ Synopsis

Intramolecular radical cyclisation protocol on 5-hexenyl systems derived from D-xylose, was utilized for the synthesis of (þ)dihydrocanadensolide, (þ)-dihydrosporothriolide and their C-3 epimers, wherein a study on the impact of C-2 0 stereocentre on radical cyclisation was conducted.

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Radical Cyclization Approach for the Syn

Radical Cyclization Approach for the Synthesis of (+)-Dihydrocanadensolide (Ia), (+)-Dihydrosporothriolide (IIa) and Their C-3 Epimers (Ib) and (IIb) from D-Xylose.

✍ G. V. M. Sharma; T. Gopinath 📂 Article 📅 2003 🏛 John Wiley and Sons ⚖ 68 KB 👁 1 views