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Radical copolymerization of acrylic monomers. IV. Effect of substituents on the radical polymerization and copolymerization of phenyl acrylates

✍ Scribed by Román, J. San ;Madruga, E. L. ;Del Puerto, M. A.


Publisher
John Wiley and Sons
Year
1983
Weight
587 KB
Volume
21
Category
Article
ISSN
0360-6376

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📜 SIMILAR VOLUMES


Radical copolymerization of acrylic mono
✍ J. San Román; E.L. Madruga 📂 Article 📅 1982 🏛 Elsevier Science 🌐 English ⚖ 427 KB

The kinetics of the copolymerization of methyl methacrylate with phenyl acrylate in solution at low conversions have been examined. The ~[H]NMR spectra of copolymers show some special features which are explained by taking into account the composition and the stereochemical configuration of copolyme

Substituent effects in free radical copo
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## Abstract Relative reactivity ratios have been determined for __o__‐chlorostyrene with five lower acrylates and methacrylates, respectively, and for methyl acrylate with a number of substituted styrenes in free‐radical copolymerization. Analysis of the data shows that: (a) acrylates are less reac