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Radical copolymerization of 2-acryloyl thioxanthone with methyl methacrylate

✍ Scribed by F. Catalina; C. Peinado; E. L. Madruga; R. Sastre; J. L. Mateo; N. S. Allen

Publisher: John Wiley and Sons
Year: 1990
Tongue: English
Weight: 353 KB
Volume: 28
Category: Article
ISSN: 0887-624X
DOI: 10.1002/pola.1990.080280502

No coin nor oath required. For personal study only.

✦ Synopsis

Abstract

A novel monomer, 2‐acryloyl thioxanthone (TXA), was prepared by reaction of 2‐hydroxy thioxanthone with acryloyl chloride. Copolymerization of TXA with methyl methacrylate (MMA) in DMF at 80°C was studied in order to evaluate relative reactivities of these monomers. Values of 1.36 and 0.5 were found for the respective reactivity ratios of MMA and TXA, respectively. The resonance stabilization and polar properties were determined and discussed in terms of spectroscopic data.

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