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Radical chemistry of thiohydroxamic acid esters

โœ Scribed by Derek H.R. Barton; Gerhard Kretzschmar

Book ID
108382393
Publisher
Elsevier Science
Year
1983
Tongue
French
Weight
175 KB
Volume
24
Category
Article
ISSN
0040-4039

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๐Ÿ“œ SIMILAR VOLUMES

Formation of carbon-carbon bonds with ra
Formation of carbon-carbon bonds with radicals derived from the esters of thiohydroxamic acids
โœ Derek H.R. Barton; David Crich; Gerhard Kretzschmar ๐Ÿ“‚ Article ๐Ÿ“… 1984 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 206 KB

Radicals formed from the esters of thiohydroxamic acids readily add to electron deficient olefins to give adducts of potential synthetic value in variable yield. In certain cases the added sulphur function is easily eliminated with reformation of olefin. Functional group manipulation in complexe na

Light induced halogenative decarboxylati
Light induced halogenative decarboxylation of thiohydroxamic esters
โœ William G. Dauben; Bruce A. Kowalczyk; Dominique P. Bridon ๐Ÿ“‚ Article ๐Ÿ“… 1989 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 159 KB

The generality of light initiated halogenative decarboxylation of thiohydroxamic esters was studied. This method gave high yields of alkyd chlorides, bromides and iodides derived from primary, secondary and tertiairy substituted carboxylic acids.