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Radical cation states of 2,3,5,6-tetramethylenenorbornane, 2,3,5,6-tetramethylenebicyclo[2.2.2]octane and of related compounds

✍ Scribed by Manijeh Mohraz; Christopher Batich; Edgar Heilbronner; Pierre Vogel; Pierre-Alain Carrupt


Publisher
Elsevier Science
Year
2010
Tongue
English
Weight
560 KB
Volume
98
Category
Article
ISSN
0165-0513

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## Abstract The photoelectron spectrum of the title compound is reported and assigned by correlation with the photoelectron spectra of related molecules.

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## Abstract Biphenyl‐2,2β€²,3,3β€²,5,5β€²,6,6′‐^2^H~8~ was prepared from biphenyl‐d~10~. Initial bromination of biphenyl‐d~10~ followed by hydrogenolysis of the 4,4′‐dibromobiphenyl‐d~8~ with lithium aluminum hydride gave the desired product in 40% overall yield.