Radical cation salts of BEDT-TTF and an unsymmetrical BEDT-TTF derivative
✍ Scribed by D. Schweitzer; K. Bender; H. Endres; S. Gärtner; R. Heid; I. Heinen; H.J. Keller; A. Weber; M. Weger
- Publisher
- Elsevier Science
- Year
- 1986
- Weight
- 295 KB
- Volume
- 143
- Category
- Article
- ISSN
- 0378-4363
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Photoluminescence spectra of the organic donor compound, bis(ethylenedithio)tetrathiafitlvalene (BEDT-TTF), has been observed in crystals and rigid solution at liquid He temperature. The spectra have similar shapes with a maximum at 1.96 eV and an intense sideband near 1.79 eV. A solid state effect
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Two new charge transfer salts of BEDT-TTF, bis (ethylenedithio) tetrathiafulvalene, with thiocyanato-metal complex anions have been synthesized and characterized as (BEDT-TTF) 4 [Fe(NCS) 6 ] ' CH 2 Cl 2 and (BEDT-TTF) 2 [Cr(NCS) 4 (bipym)] ' 0.15H 2 O, where bipym ؍ 2,2-bipyrimidine. The Fe salt,