Through-bond interaction in the radical
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A.M. Brouwer; F.W. Langkilde; K. Bajdor; R. Wilbrandt
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Article
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1994
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Elsevier Science
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English
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The radical cation of N,Ndimethylpiperazine is investigated by resonance Raman spectroscopy and ab initio calculations. The calculations strongly support the assignment of the vibrational spectrum to a chair conformation. It is shown that a dramatic geometry relaxation following ionization allows a