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Radical cation Cope rearrangement of 1,5-hexadiyne to 1,2,4,5-hexatetraene (bis(allene)) at 77 K

✍ Scribed by Dai, Sheng; Pappas, Robert S.; Chen, Guo Fei; Guo, Qing Xiang; Wang, Jih Tzong; Williams, Ffrancon


Book ID
121309689
Publisher
American Chemical Society
Year
1989
Tongue
English
Weight
426 KB
Volume
111
Category
Article
ISSN
0002-7863

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ESR studies of local concentrations of r
✍ Keichi Nunome; Hachizo Muto; Kazumi Toriyama; Machio Iwasaki πŸ“‚ Article πŸ“… 1976 πŸ› Elsevier Science 🌐 English βš– 450 KB

The microwxtie power saturation behaviour of alkyl radicals in polyethylene irradiated at l&4.2 and 77 K suggests that the local .concentrations of radicals in spurs is considerably higher in the samples irradiated at 1.5 and 4.2 K. Upon annealing the samples at 77 K, the local concentrations became