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Radical cation chain oxygenation of dienes by triplet oxygen

โœ Scribed by Nelsen, Stephen F.; Teasley, Mark F.; Kapp, Daniel L.

Book ID
111930808
Publisher
American Chemical Society
Year
1986
Tongue
English
Weight
942 KB
Volume
108
Category
Article
ISSN
0002-7863

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๐Ÿ“œ SIMILAR VOLUMES

Reaction path calculations for the inter
Reaction path calculations for the interaction of the ethylene radical cation with triplet oxygen
โœ Chia-Chung Chen; Marye Anne Fox ๐Ÿ“‚ Article ๐Ÿ“… 1983 ๐Ÿ› John Wiley and Sons ๐ŸŒ English โš– 409 KB ๐Ÿ‘ 1 views

UMNDO reaction path calculations for trapping of the ethylene-cation radical with ground state oxygen suggest that formation of a dioxetane radical cation proceeds through the intermediacy of a peroxycation radical. The predicted enthalpy of activation (Aโ‚ฌโ‚ฌ% = 13.8 kcal/mol) is consistent with rapid