Radical-cation acidities in solution and in the gas phase
β Scribed by Bordwell, Frederick G.; Cheng, Jin Pei
- Book ID
- 127088662
- Publisher
- American Chemical Society
- Year
- 1989
- Tongue
- English
- Weight
- 544 KB
- Volume
- 111
- Category
- Article
- ISSN
- 0002-7863
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π SIMILAR VOLUMES
200 mL) was acidified with 3 drops of 32% HCI and stirred for 15 min at 50Β°C (exclusion of light). After extraction with CH,CI,, the organic phase was dried (Na,SO,) and purified on silica gel (20 8). After removal of the solvent there remained 0.53 g (72%) of a crystalline product. For further puri
The gas-phase acidity of ionized benzyl alcohol and of some of its derivatives with selected reference bases has been studied by Fourier Transform Ion Cyclotron Resonance (FT-ICR) mass spectrometry. The aim was to relate the gas-phase reactivity to the behavior in aqueous solution of the radical cat