Radical annulations with nitriles: Novel cascade reactions of cyano-substituted alkyl and sulfanyl radicals with isonitriles
✍ Scribed by Carlo Maurizio Camaggi; Rino Leardini; Daniele Nanni; Giuseppe Zanardi
- Publisher
- Elsevier Science
- Year
- 1998
- Tongue
- French
- Weight
- 742 KB
- Volume
- 54
- Category
- Article
- ISSN
- 0040-4020
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📜 SIMILAR VOLUMES
New radical annulation reactions are described involving addition of orrho-cyano-substituted aryl radicals to alkynes. Addition of the aryl radical to the C-C triple bond gives rise to a vinyl radical, whose cyclisation onto the carbon atom of the nitrile moiety produces an iminyl radical. The final
## Abstract ChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 100 leading journals. To access a ChemInform Abstract of an article which was published elsewhere, please select a “Full Text” option. The original article is trackable v
## Abstract Only a limited amount of work has been previously published concerning the free radical polymerisation of 4‐methoxystyrene and 4‐methylstyrene initiated by 2,2′‐azoisobutyronitrile (2,2′‐azobis(2‐methylpropiononitrile)) (AIBN). The present investigation was, therefore, undertaken to est