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Radical-anion reactions. The reductive dimerization of 1,3-cyclohexadiene by sodium-ammonia

✍ Scribed by D.Y. Myers; R.R. Grabbe; P.D. Gardner


Publisher
Elsevier Science
Year
1973
Tongue
French
Weight
175 KB
Volume
14
Category
Article
ISSN
0040-4039

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3-and 4-Hydroxycoumarin (& and 2) as well as 2-hydroxy-2,5-cyclohexadien-l-ones a-6 were reacted with K02/18-crown-6 in benzene. Initial deprotonation of the enol hydrogen was followed by nucleophilic attack by 0 sulting anion (for 4 and ,&-q). A convenieng CONDITION\* YIELD (2) && KO (5 hr) KOS (16