Anthracene-labelled poly(methy1 methacrylate) (PMMA) was prepared via atom transfer radical polymerization (ATRP) where 9,10-bis(chloromethyl)anthracene and CuC1/2,2'-bipyridine were used as the initiator and catalyst, respectively. Both the linear increase of the number average molecular mass with
Radical anion mechanism for chain scission of poly(methyl methacrylate) via electron transfer
β Scribed by Wataru Sakai; Akira Tsuchida; Masahide Yamamoto; Tomochika Matsuyama; Hitoshi Yamaoka; Jun Yamauchi
- Publisher
- John Wiley and Sons
- Year
- 1994
- Tongue
- English
- Weight
- 342 KB
- Volume
- 15
- Category
- Article
- ISSN
- 1022-1336
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## Abstract **Summary:** Experimental and modeling studies of additionβfragmentation chain transfer (AFCT) during radical polymerization of methyl methacrylate in the presence of poly(methyl methacrylate) macromonomer with 2βcarbomethoxyβ2βpropenyl __Ο__βends (PMMAβCO~2~Me) at 60βΒ°C are reported. T