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Radical and polar mechanisms for exchange of iodine with organic iodides

โœ Scribed by Noyes, Richard M.; Koros, Endre


Book ID
121226217
Publisher
American Chemical Society
Year
1971
Tongue
English
Weight
881 KB
Volume
4
Category
Article
ISSN
0001-4842

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Exchange and decomposition reactions of
โœ Masato Nakashima; Richard M. Noyes ๐Ÿ“‚ Article ๐Ÿ“… 1969 ๐Ÿ› John Wiley and Sons ๐ŸŒ English โš– 422 KB

In the presence of elementary iodine, isobutyl iodide (2-methyl-1-iodopropane) undergoes isotopic exchange and also decomposes with production of additional iodine. Both reactions are approximately first order in isobutyl iodide and half order in iodine molecules. I n degassed hexachlorobutadiene at