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Radical [3 + 2] Annulation of N -Allyl- N -chlorotosylamide with Alkenes via Atom-Transfer Process

✍ Scribed by Tsuritani, Takayuki; Shinokubo, Hiroshi; Oshima, Koichiro


Book ID
121859845
Publisher
American Chemical Society
Year
2001
Tongue
English
Weight
42 KB
Volume
3
Category
Article
ISSN
1523-7060

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## Abstract The kinetics and controllability of the Ti[OCH~2~CCl~3~]~4~‐initiated atom transfer radical polymerization (ATRP) of __n__‐butyl acrylate were investigated. Then, with Ti[OCH~2~CCl~3~]~4~ as the initiator, poly(ϡ‐caprolactone)‐__block__‐poly(__n__‐butyl acrylate) (PCL‐__b__‐PBA) copolym