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Radiative and radiationless transitions in solutions of rare earth ions: Vibrational coupling of H2O and D2O to electronic levels of Gd3+

✍ Scribed by Y. Haas; G. Stein

Publisher
Elsevier Science
Year
1971
Tongue
English
Weight
290 KB
Volume
11
Category
Article
ISSN
0009-2614

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✦ Synopsis

The viironic satellites due to coupling with OH or OD vibrations of the 312 run fluorescent emkion line from the 6P ,,1 excited level of Gd3+ in aqueous solution of the perchlorate salt were observed. in Hz0 the shifts mnespond to the OH stretching (and Hz0 ber&g) frequencies, with correspondingly decreased shifts in D20. The co~ecthn with radiationless transitions is discus&.

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