The emission following single-photon excitation of the first excited singlet state of acetone was studied. Stis muhi-exponential and extremely prm sensitive. vibrationally hot triplet molecules above the singlet origin decay significantly faster than those below. At 91.5 f 0.5 kcal/mole above the gr
β¦ LIBER β¦
Radiative and collisional processes in CNA2
β Scribed by Joshua B. Halpern; Yuhui Huang; Tatiana Titarchuk
- Publisher
- Springer Netherlands
- Year
- 1996
- Tongue
- English
- Weight
- 351 KB
- Volume
- 236
- Category
- Article
- ISSN
- 0004-640X
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Lifetimes of excited vibronic levels in NCNO are measured both by LIF and by monitoring excited state absorptions. Fluorescence lifetimes are longer than S, radiative lifetimes at all wavelengths between the band origin (11339 cm-' ) and Da (17085 cm-' ). In the language of radiationless transitions