Radiation synthesis and environmental responsiveness of semi-interpenetrating polymer networks composed of poly(dimethyl–aminoethyl methacrylate) and poly(ethylene oxide)

✍ Scribed by Zhugen Liu; Min Yi; Maolin Zhai; Hongfei Ha; Zhifu Luo; Xueqing Xiang

• Publisher: John Wiley and Sons
• Year: 2004
• Tongue: English
• Weight: 89 KB
• Volume: 92
• Category: Article
• ISSN: 0021-8995
• DOI: 10.1002/app.20319

✦ Synopsis

Abstract

Semi‐interpenetrating polymer networks (semi‐IPNs) composed of poly(dimethyl–aminoethyl methacrylate) (PDMAEMA) and poly(ethylene oxide) (PEO) were synthesized by γ‐radiation; three semi‐IPNs with 80 : 20, 90 : 10, and 95 : 5 weight ratios of DMAEMA/PEO were obtained by use of this technique. The gel–dose curves showed that the hydrogels were characterized by a structure typical of semi‐IPNs and the results of elemental analysis supported this point. The temperature‐induced phase transition of semi‐IPNs with the composition of 95 : 5 was still retained, with the lower critical solution temperature of PDMAEMA shifting from 40 to 27°C. The temperature sensitivity of the other two semi‐IPNs gradually disappeared. The pH sensitivity of three semi‐IPNs was still retained but the pH shifted slightly to lower values with increasing PEO content in the semi‐IPNs. The effect of PEO content in semi‐IPNs on their environmental responsiveness was discussed. © 2004 Wiley Periodicals, Inc. J Appl Polym Sci 92: 2995–3001, 2004