✍ Scribed by N.N. Rozovskaya; A.P. Sheinker; A.D. Abkin
No coin nor oath required. For personal study only.
📜 SIMILAR VOLUMES
The kinetics of free radical polymerizations of methyl and butyl acrylate were studied in benzene at 50:. The initiation rate constant determined by the inhibition method was found to be constant over the whole monomer solvent composition range in both systems. The polymerization rate was investigat
## Abstract Summary: Reversible addition fragmentation chain transfer (RAFT) polymerizations of methyl acrylate (MA) in solution containing either 22 vol.‐% CO~2~ or toluene were performed at 80 °C and 300 bar using cumyl dithiobenzoate (CDB) at concentrations between 1.8 × 10^−3^ to 2.5 × 10^−2^ m
The kinetics of methyl acrylate polymerization initiated by azobisisobutyronitrile were investigated in dimethylformamide at 40-60. The polymerization was 1/2 order with respect to initiator; the rate of initiation was independent of the initial concentration of monomer. The rate and the overall rat
Solution copolymerizations of butyl acrylate/methyl methacrylate in toluene were performed over an expanded temperature range (60 -140°C) compared to more typical ranges that do not exceed 80°C. From a large amount of data collected independently at two laboratories, reactivity ratios were estimated
The rate enhancing effects of aromatic solvents (1-fluoro-, 1-chloro-, l-bromonaphthalene and toluene) on the photo-and thermal sensitized polymerization of methyl methacrylate by azoinitiators at 25 ° and 60 ° respectively were investigated by measuring ko, k, and R, by means of rate, molecular wei