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Radiation-Initiated Codimerization of Methallyl Chloride with Unsaturates

โœ Scribed by Gale, L. H.


Book ID
126297642
Publisher
American Chemical Society
Year
1966
Tongue
English
Weight
776 KB
Volume
31
Category
Article
ISSN
0022-3263

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Synthesis of ฮฒ,ฮณ-unsaturated phenyl este
โœ Mayr, Herbert ;Gabriel, Andreas O. ;Schumacher, Ralf ๐Ÿ“‚ Article ๐Ÿ“… 1995 ๐Ÿ› John Wiley and Sons ๐ŸŒ English โš– 471 KB

## Abstract Phenyl chloroformate (1) reacts with the allylsilanes 2aโ€“h in the presence of aluminium chloride to give the ฮฒ,ฮณโ€unsaturated phenyl esters 3aโ€“h in 50โ€“90% yield. While these reactions proceed in the usual manner with allylic inversion, (1,1โ€dimethylallyl)trimethylsilane (2i) reacts with