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Radiation-induced polymerization at high pressure of 2,3,3,3-tetrafluoropropene in bulk and with tetrafluoroethylene

✍ Scribed by Brown, Daniel W. ;Lowry, Robert E. ;Wall, Leo A.


Publisher
Wiley (John Wiley & Sons)
Year
1971
Tongue
English
Weight
732 KB
Volume
9
Category
Article
ISSN
0449-296X

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Radiation-induced polymerization of 3,3,
✍ Brown, Daniel W. ;Lowry, Robert E. ;Wall, Leo A. πŸ“‚ Article πŸ“… 1970 πŸ› Wiley (John Wiley & Sons) 🌐 English βš– 507 KB

## Abstract A study was made of the radiation‐induced polymerization under pressure of 3,3,4,4,5,5,5‐heptafluoropentene‐1. Polymerization rates increase with pressure (activation volume equals βˆ’ 11 cc/mole) and temperature (activation enthalpy equals 6.5 kcal/mole) in liquid phase. At 13800 atm and