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Radiation-induced network formation in polymers

✍ Scribed by V. I. Dakin

Publisher
John Wiley and Sons
Year
1996
Tongue
English
Weight
671 KB
Volume
59
Category
Article
ISSN
0021-8995

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✦ Synopsis

The topological approach to radiation crosslinking of polymers is based on research of the transition from one topological form of macromolecules to another form, especially from a branched to a network form. The different types of transition and different threshold doses are considered. On the basis of the statistical physics of macromolecules, a conclusion about the network formation through cycles of definite size was made. The dependence of properties of radiation-crosslinked polymers on characteristics of topological forms was studied. The characteristics of topological forms for some polymers [poly(vinylchloride), block copolymers, and polyethylene] were determined. 0 1996 John Wiley & Sons, Inc.

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