Radiation-chemical carboxylation of formic acid and methanol in aqueous solution
✍ Scribed by N. Getoff; F. Gütlbauer; G.O. Schenck
- Publisher
- Elsevier Science
- Year
- 1966
- Weight
- 737 KB
- Volume
- 17
- Category
- Article
- ISSN
- 0020-708X
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The Raman spectra of 'neat' formic acid and formic acid in several solvents (water, acetonitrile, 1,4dioxane and dichloromethane) were measured. In aqueous solution a very clear non-coincidence effect (NCE) indicative of resonance energy transfer was observed. The size of the NCE (ca 64 cm -1 ) indi
The kinetics of the permanganate oxidation of formic acid in aqueous perchloric acid a t 30°C were examined by the spectrophotometric method. The chemical reaction 2Mn0, A BHCOOH + 2H + -2Mn02 + 3C0, + 4H20. appears to proceed via several parallel reactions. The overall rate equation has been obtain