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Racemic and optically active 1,1′-binaphthyl-2,2′-diyl sulfite: Synthesis, crystal structure, and ring-opening reactions with selected nucleophiles

✍ Scribed by Jozef Drabowicz; Dorota Krasowska; Bernard Marciniak; Ewa Rozycka-Sokolowska

Publisher: John Wiley and Sons
Year: 2011
Tongue: English
Weight: 316 KB
Volume: 22
Category: Article
ISSN: 1042-7163
DOI: 10.1002/hc.20722

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✦ Synopsis

Abstract

Preparation of the sulfite derived from racemic and (R)−(+)‐enantiomer of BINOL is reported. The crystal structure of the optically active, levorotatory sulfite isomer and its ring opening induced by nucleophilic substitution reactions with selected nucleophiles are presented. © 2011 Wiley Periodicals, Inc. Heteroatom Chem 22:562–570, 2011; View this article online at wileyonlinelibrary.com. DOI 10.1002/hc.20722

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