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Racemic (1SR,2SR,7aRS)-1,2,7a-trihydr­oxy-2-methyl­perhydro-1-phosphaindene 1-oxide monohydrate

✍ Scribed by Kruszynski, Rafal ;Trzesowska, Agata ;Majewski, Piotr ;Bodalski, Ryszard

Publisher
International Union of Crystallography
Year
2005
Tongue
English
Weight
200 KB
Volume
61
Category
Article
ISSN
1600-5368

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✦ Synopsis

In the title racemic compound, C 9 H 19 O 5 P, all interatomic C-C and C-OH distances can be considered normal. The P-O and P O distances are 1.5583 (8) and 1.5003 (7) A ˚, respectively. The rings are cis-fused, the phospholane ring exists in a slightly distorted envelope conformation and the cyclohexane ring adopts an almost ideal chair conformation. All hydroxyl groups are anti to the P O bond. Molecules are linked via medium-strength intermolecular O-HÁ Á ÁO hydrogen bonds into a three-dimensional network.

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✍ Peter Höhn; Rüdiger Kniep 📂 Article 📅 2002 🏛 John Wiley and Sons 🌐 German ⚖ 605 KB

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