Single-crystal X-ray study T = 153 K Mean '(C±C) = 0.002 A Ê R factor = 0.039 wR factor = 0.116 Data-to-parameter ratio = 17.0 For details of how these key indicators were automatically derived from the article, see http://journals.iucr.org/e.
rac-(1S,6S)-Methyl 6-methyl-2-oxobicyclo[4.1.0]heptane-1-carboxylate
✍ Scribed by Juhl, Martin ;Søtofte, Inger
- Publisher
- International Union of Crystallography
- Year
- 2007
- Tongue
- English
- Weight
- 108 KB
- Volume
- 63
- Category
- Article
- ISSN
- 1600-5368
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📜 SIMILAR VOLUMES
The bicyclo[3.1.0]hexane fragment of the title molecule, C 9 H 12 O 4 , adopts a boat-like conformation, with its methoxycarbonyl substituent in the endo position. In the crystal structure, molecules form centrosymmetric OÐHÁ Á ÁO hydrogen-bonded dimers, which are arranged in layers.
Single-crystal X-ray study T = 83 K Mean '(C±C) = 0.004 A Ê R factor = 0.041 wR factor = 0.092 Data-to-parameter ratio = 9.0 For details of how these key indicators were automatically derived from the article, see http://journals.iucr.org/e.
The title compound, C 14 H 16 N 2 O 2 , was obtained from the reaction between S-tryptophan methyl ester hydrochloride and acetaldehyde. The molecule adopts a trans configuration, with the methyl and methoxycarbonyl groups located on opposite sides of the central tetrahydro--carboline unit. Bifurcat