3-Methyl-r-butyrolactone has been enployed as a source of Z-methyl-3-hydroxyketones after functioning as a tenplate for the preparation of enantiomerically pure propionate chains. This method is exemplified by the preparation of the C&,-C27 propionate fragment utilized by Kishi in his synthesis of r
✦ LIBER ✦
R-3-methyl-γ-butyrolactone as a template for the synthesis of (+)-invictolide
✍ Scribed by Frederick E. Ziegler; Eugene P. Stirchak; Ronald T. Wester
- Book ID
- 104218307
- Publisher
- Elsevier Science
- Year
- 1986
- Tongue
- French
- Weight
- 192 KB
- Volume
- 27
- Category
- Article
- ISSN
- 0040-4039
No coin nor oath required. For personal study only.
📜 SIMILAR VOLUMES
3-Methyl-γ-butyrolactone as a source of
✍
Frederick E. Ziegler; Alyssa Kneisley
📂
Article
📅
1987
🏛
Elsevier Science
🌐
French
⚖ 251 KB
(R)-(+)-β-Veratryl-γ-butyrolactone. A ne
✍
Eric Brown; Alain Daugan
📂
Article
📅
1986
🏛
Elsevier Science
🌐
French
⚖ 233 KB
The effect of γ-irradiation on deoxyribo
✍
Masanobu Hayashi; Takao Kobayashi; Giichi Yoshii
📂
Article
📅
1974
🏛
Elsevier Science
⚖ 266 KB
Formal synthesis of (-)-calcimycin (A-23
✍
Ziegler, Frederick E.; Cain, William T.
📂
Article
📅
1989
🏛
American Chemical Society
🌐
English
⚖ 983 KB
A chemoenzymatic approach to the synthes
✍
Sang-Hyun Lee; Oh-Jin Park; Hong-Sun Uh
📂
Article
📅
2008
🏛
Springer
🌐
English
⚖ 191 KB
Absolute Configuration and Synthesis of
✍
Schulz, Stefan
📂
Article
📅
1992
🏛
John Wiley and Sons
🌐
English
⚖ 642 KB
## Abstract 2‐Hydroxy‐2‐(1‐hydroxyethyl)‐3‐methyl‐γ‐butyrolactone (1) is a constituent of scent glands of male ithomiine butterflies. All diastereomers and the respective (3__R__)‐enantiomers were synthesized by starting from __rac__‐ or (3__S__)‐3‐methyl‐γ‐butyrolactone 3. Their relative configura