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(R)-1-(2-Hydroxy-5-methylphenyl)-N-[(S)-1-(2-methoxy-5-methylphenyl)-2-phenylethyl]butan-1-aminium chloride

✍ Scribed by Zhang, Guang-You ;Li, Ming ;Wang, Wan-Hui ;Gu, Xun-Gang

Publisher
International Union of Crystallography
Year
2007
Tongue
English
Weight
958 KB
Volume
63
Category
Article
ISSN
1600-5368

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✦ Synopsis

2-{(R)-1-[(S)-1-(2-Methoxy-5-methylphenyl)-2-phenylethylamino]butyl}-4-methylphenol has been synthesized and its absolute configuration determined from the crystal structure of its hydrochloride, the title compound, C~27~H~34~NO~2~
^+^·Cl^−^. The absolute configuration of the stereogenic center that carries the 2-methoxy-5-methylphenyl substituent was found to be R. Intermolecular N—H...Cl and O—H...Cl and intramolecular N—H...O hydrogen bonds stabilize the structure.

📜 SIMILAR VOLUMES

N′-[(1E)-1-(2-Hydroxy-5-methylphenyl)eth
N′-[(1E)-1-(2-Hydroxy-5-methylphenyl)ethylidene]-4-methoxybenzohydrazide
✍ Chang, Jian-Guo ;Ji, Chang-You 📂 Article 📅 2007 🏛 International Union of Crystallography 🌐 English ⚖ 645 KB

The title compound, C 17 H 18 N 2 O 3 , displays a trans conformation with respect to the C N double bond. The crystal structure is stabilized by intramolecular O-HÁ Á ÁN and intermolecular N-HÁ Á ÁO hydrogen bonds.

Molecular dynamics of cis-1-(2-hydroxy-5
Molecular dynamics of cis-1-(2-hydroxy-5- methylphenyl)ethanone oxime and N-(2-hydroxy-4-methylphenyl)acetamide in solution studied by NMR spectroscopy
✍ Ibrahim Garib Mamedov; Uwe Eichhoff; Abel Mammadali Maharramov; Musa Rza Bayramo 📂 Article 📅 2010 🏛 John Wiley and Sons 🌐 English ⚖ 238 KB

## Abstract The formation of hydrogen bonds and molecular dynamics for the molecules __cis__‐1‐(2‐hydroxy‐5‐methylphenyl)ethanone oxime (**I**) and __N__‐(2‐hydroxy‐4‐methylphenyl)acetamide (**II**) have been investigated in solution using NMR. The results confirm the formation of OH···O, OH···N

2(R)-Hydro­xy-4-(4-methoxy­benzoyl)-2-me
2(R)-Hydro­xy-4-(4-methoxy­benzoyl)-2-methoxy­carbonyl­methyl-5-(4-methoxy­phenyl)-1-(2-methyl­phenyl)-2,3-di­hydro-1H-3-pyrrolone
✍ Öztürk, Sema ;Saçmacı, Mustafa ;Üngören, Şevket Hakan ;Akkurt, Mehmet ;Fun, Hoon 📂 Article 📅 2003 🏛 International Union of Crystallography 🌐 English ⚖ 205 KB

The title compound, C 29 H 27 NO 7 , has a non-planar con®guration. The methoxycarbonylmethyl group exhibits an E con®guration. The crystal structure is stabilized by intermolecular OÐHÁ Á ÁO and CÐHÁ Á ÁO contacts.