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Quintuply-Bonded Dichromium(I) Complexes Featuring Metal–Metal Bond Lengths of 1.74 Å

✍ Scribed by Chia-Wei Hsu; Jen-Shiang K. Yu; Chun-Hsu Yen; Gene-Hsiang Lee; Yu Wang; Yi-Chou Tsai

Book ID
101567608
Publisher
John Wiley and Sons
Year
2008
Tongue
English
Weight
437 KB
Volume
47
Category
Article
ISSN
0044-8249

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Correlation of metal-metal bond lengths
Correlation of metal-metal bond lengths and metal orbital ionization energies in dichromium(ii) and dimolybdenum(ii) complexes
✍ Madeleine Berry; C.David Garner; Ian H. Millier; Alistair A. Macdowell; Ian B. W 📂 Article 📅 1980 🏛 Elsevier Science 🌐 English ⚖ 302 KB

The dlfference between the metal-metal 6 and TT orbItal lonlzation energws for the complexes M~(OZCCF&, M2(02CCH3)4, M2(CaHsf.+\_ and Mz(hlHP)1, (where M = Cr or MO and H{MHP)= 6-methyl-2-hydrouypyrtdme) mcreases, wtthm each series. as the metal-metal bond length decreases. The vanahon m the metal-m