Quinolin-8-aminium toluene-4-sulfonate
✍ Scribed by Smith, Graham ;Wermuth, Urs D. ;Healy, Peter C.
- Publisher
- International Union of Crystallography
- Year
- 2004
- Tongue
- English
- Weight
- 151 KB
- Volume
- 60
- Category
- Article
- ISSN
- 1600-5368
No coin nor oath required. For personal study only.
📜 SIMILAR VOLUMES
In the cation of the title compound, C 16 H 14 NO 3 S + ÁC 7 H 7 O 3 S À , the quinolinium ring system makes a dihedral angle of 69.14 (9) with the benzene ring.
The molecular packing of the title compound, C 15 H 11 N 2 O 3 S, is stabilized by a hydrogen-bonded network. The H atoms of the amino group form intermolecular N-HÁ Á ÁN [2.13 (3) A ˚] and N-HÁ Á ÁO [2.46 (3) A ˚] hydrogen bonds. The sulfonyl O atoms are each also involved in intermolecular C-HÁ Á
The nearly planar aminoquinoline fragment and the aromatic ring of the triisopropylbenzenesulfonate group of the title compound, C 24 H 30 N 2 O 3 S, form a dihedral angle of 47.9 (2) . Both H atoms of the amino group are involved in intermolecular hydrogen bonds of types N-HÁ Á ÁO (2.56 A ˚) and N-