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Quinazolines and 1,4-benzodiazepines. LIX. Preparation of pyrrolo[2,1-c]-1,4-benzodiazepines

✍ Scribed by Walser, Armin; Silverman, Gladys; Fryer, R. Ian


Book ID
125510182
Publisher
American Chemical Society
Year
1973
Tongue
English
Weight
786 KB
Volume
38
Category
Article
ISSN
0022-3263

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Quinazolines et benzodiazépines-1,4. LX
✍ Roland Jaunin; Wolf Arnold 📂 Article 📅 1973 🏛 John Wiley and Sons 🌐 German ⚖ 978 KB

## Abstract Upon treatment with oxalyl chloride followed by reaction with the appropriate nucleophile, the 3‐carbamoyl‐benzodiazepines **6**, **7** and **8** were converted stereospecifically to the tricyclic compounds **12, 13, 14, 16** and **19**. Epimerization of **19** in presence of __p__‐tolu