✦ LIBER ✦

Quenching of pyrene fluorescence by cupric ions in micellar solution: Effect of quenching on the polarity reported by the probe

✍ Scribed by J. Jay; L.J. Johnston; J.C. Scaiano

Publisher: Elsevier Science
Year: 1988
Tongue: English
Weight: 473 KB
Volume: 148
Category: Article
ISSN: 0009-2614
DOI: 10.1016/0009-2614(88)80324-5

No coin nor oath required. For personal study only.

✦ Synopsis

The ratio of peak III to peak I intensities of the so-called III and I fluorescence bands of pyrene increases dramatically when cupric ions are used as quenchers for pyrene emission in sodium dodecyl sulfate micelles. These results indicate a decrease in the polarity sensed by the probe when its lifetime is reduced and are attributed to the interdependence of kinetic and spectroscopic parameters.

* Issued as NRCC 28746.

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