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Quenching of acetone triplets by 1,3-dienes in fluid solution

โœ Scribed by Nicholas J. Turro; Yoshifumi Tanimoto


Publisher
Elsevier Science
Year
1980
Weight
330 KB
Volume
14
Category
Article
ISSN
0047-2670

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The rate constants for quenching of the triplet states of eleven different aromatic hydrocarbons by copper(I1) bis(2,4-pentanedionate) and copper(U) bis( l,l, 1,5,5,5-hexafluoro-2,4-pcntanedionate) in solution have been measured by laser flash photolysis. The involvement of electron-and energy-trans

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## Abstract Sensitization of neat __cis__ or __trans__ 1,3โ€pentadienes by triplet benzophenone leads only to isomerization and dimerization. The quantum yields measured for these processes as well as the photostationary composition are strikingly different from the figures obtained in dilute soluti