Quelques propriétés d'oxydes de manganèse obtenus par décomposition thermique
✍ Scribed by Karl-Joachim Euler; Robert Kirchhof
- Publisher
- Elsevier Science
- Year
- 1981
- Tongue
- English
- Weight
- 425 KB
- Volume
- 26
- Category
- Article
- ISSN
- 0013-4686
No coin nor oath required. For personal study only.
✦ Synopsis
R&u&Par
dtimposition thermique du nitrate de mangarkse on obticnt, &on les conditions de d&composition, dcs pr@arations difikentes, mais qui sent composk, en principle, de &MnO, (pyrolusite).
Leur teneur en cau varie
entre 0 et 5 pourcent. Tous ces produits ont une activitk faiblc et une conductibilitk assez tlevfxx. Si on ajoute, au contraire, du citrate ou du gluconate de manganlse, la dkcomposition conduit ZI la formation de a-Mn,O, ou meme MnsO,, contenant moins de 1 pourcent d'eau, et ayant une conductibilitk Mectriquc t&s basse. Abmtrrct-Thermal decomposition of manpnous nitrate results in the formation of jCMn0, (pyrolwite). Variation of the conditions is accompanied by a certain variation of the properties. but the principal component is p-MnO,. The water content is between 0 and 5 per cent. In general, the specimens show low activity, and aregoodconductors.Alrcadysmallamountsofmanganouscitrateorgluconateaddod, however, result in theformationofpoorconductingrr-Mn20,0r Mn,O*havinga watercontent ofless than 1 percent. PARTIE EXPERIMENTALE 1. Oxydes obtenus par decomposition du nitrate de mangant?se * Nous remercions vivement Monsieur Ic Doctcur Alfred Schmier pour ses remarques t&s valables. + Dsns la litt&sturc[2 101 ectte phase Cdt dtnot& came modification partieuli&re, nommk cMn0,. Mai cztte phase dil& peu ou point du tout de la grande famille des y-MnO, .
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